Hi. I realize that you need this issue resolved immediately. I have moved your post here in this forum.
No, there's no setting or policy with the switch to using the POP3 settings. I suggest that you first re-configure your account in your e-mail client. If the problem persists, contact your e-mail client's support team as it may have settings that do this behavior.
POP3 settings:
http://windowslivehelp.com/solutions/settings/archive/2009/01/06/send-and-receive-windows-live-hotmail-emails-from-a-mail-client.aspx